Before Angelina Jolie was a part of “Brangelina,” she was creating her own headlines  - locking lips with her brother at the 2000 Oscars, admitting to relationships with both men and women, and who could forget when she and Billy Bob Thorton were carrying around vials of each other’s blood! Since then, Angelina has since turned from wild red carpet antics to enjoying her relationship with partner, Brad Pitt, and their family of six – three adopted (Maddox, Pax, and Zahara) and three conceived with Brad (Shiloh, Knox, and Vivienne).  However, such a large brood hasn’t stopped Angelina from continued blockbuster success and her humanitarian efforts as the U.N. goodwill ambassador.